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簡要描述： Astec CHIRALDEX B-DA SUPELCO 手性氣相色譜柱毛細管柱Supelco（色譜科）位于美國賓夕法尼亞州，是Sigma-Aldrich集團下屬的子品牌，Supelco一直通過提供更新的，更可靠的色譜產(chǎn)品和來幫助色譜工作者來解決問題，其涉及的領(lǐng)域和行業(yè)有環(huán)境、食品、飲料、政府、醫(yī)藥、化工等

詳細介紹

Astec CHIRALDEX B-DA SUPELCO 手性氣相色譜柱毛細管柱

CD Type: α (alpha)
Derivative: Dialkyl
Tep. Liits: -10 °C t 200 °C (istheral) r 220 °C (prgraed)

Incrprates a phase cnsisting f a 2,6-di-O-pentyl-3-ethxy derivative f β-cycldextrin. This phase is gd fr separatins f hetercyclic aines. It has different selectivity fr ther phases and ften shws reversal in elutin fr the PH phases.

The dipentylated derivatives f alpha, beta and gaa cycldextrin shw prnunced selectivity differences based n the size, shape and functinality f the analyte. Strng evidence exists fr inclusin cplexatin which is the basic driving echanis and, therefre, reslutin is affected by saple lad. The beta-cycldextrin fr has the bradest applicability. Saple vlues under 1 icrliter at cncentratins f 5 g/L are typical with the 100/1 split rati.

Features:

Hydrphbic surface
Prnunced selectivity differences based n analyte size, shape and functinality
Separates hetercyclic aines
Different selectivity fr ther cycldextrin derivatives
Often shws reversal in elutin rder fr PH series

Selectivity pririties:

Alpha…Siple epxides, cyclic ethers, linear substituted alkanes
Beta…Hetercyclic aines
Gaa…Naphthyl analgs

Mechanis Observatins:

Strnger inclusin fr DA and, therefre, size selectivity is iprtant.
Critical teperature dependence fr enantiselectivity. Abve this teperature n separatin ccurs.

Astec CHIRALDEX B-DA SUPELCO 手性氣相色譜柱毛細管柱

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