詳細(xì)介紹
Astec CHIRALDEX G-TA SUPELCO 手性氣相色譜柱 毛細(xì)管柱
- CD Type: γ (gaa)
- Derivative: Trifluracetyl
- Tep. Liits: -10 °C t 180 °C (istheral r prgraed)
Incrprates a phase cnsisting f a 2,6-di-O-pentyl-3-trifluracetyl derivative f γ-cycldextrin.
Trifluracetylatin f the 3 psitin hydrxyl grups after pentylatin f the 2,6 hydrxyl grups creates a phase with high selectivity fr xygen cntaining analytes in the fr f alchls, ketnes, acids, aldehydes, lactnes, and halgenated cpunds.
Features:
- Separates the widest variety f enantiers
- Separates the greatest nuber f enantiers
- Gaa re selective than beta fr
- Unique retentin behavir
- Extrardinary versatility and chiral selectivity
Analytes:
Useful fr hlgus series f:
- Ain acids (priary, secndary, aratic and aliphatic)
- Aines (priary, secndary, cyclic, aratic and halgenated)
- Ain alchls
- Alkanes, hydrgenated alkanes
- Alchls (aliphatic and aratic)
- Acids (halgenated and hydrxy)
- Esters (aratic, aliphatic, hydrxy, di-ester)
- Dils
- Lactnes
- Ketnes
- Phthalides
- Sulfxides
Mechanis Observatins:
Strng diple-diple interactinsLnger alkyl chain; greater retentin; increase in enantiselectivity up t C4/C5Halgens knwn t favr cavity interactin
Diple-diple interactins are cnly identified in the echanis f separatin fr TA phases. In a hlgus series f alkane enantiers, identical alpha values are bserved regardless f chain length r branching indicating nly 1 r 2 carbns ay be cntributing t chiral recgnitin. Alpha values are greatly affected by size and plarity f the head grup. Functinal grups like epxides, ain alchls and alchls can dictate the cycldextrin selectin. Aldehydes, carbxylic acids and epxides separate better n the gaa while alchls, alchl aines and ther linear lecules separate better n the beta derivative.
Included in GC Screening Kit 71030AST.
Astec CHIRALDEX G-TA SUPELCO 手性氣相色譜柱 毛細(xì)管柱
訂貨信息:
| Prduct # | Descriptin |
| 73031AST | Astec? CHIRALDEX? G-TA 毛細(xì)管氣相色譜柱 L × I.D. 10 × 0.25 , df 0.12 μ |
| 73032AST | Astec? CHIRALDEX? G-TA 毛細(xì)管氣相色譜柱 L × I.D. 20 × 0.25 , df 0.12 μ |
| 73033AST | Astec? CHIRALDEX? G-TA 毛細(xì)管氣相色譜柱 L × I.D. 30 × 0.25 , df 0.12 μ |
| 73034AST | Astec? CHIRALDEX? G-TA 毛細(xì)管氣相色譜柱 L × I.D. 40 × 0.25 , df 0.12 μ |
| 73035AST | Astec? CHIRALDEX? G-TA 毛細(xì)管氣相色譜柱 L × I.D. 50 × 0.25 , df 0.12 μ |
Astec CHIRALDEX G-TA
17。。cn
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